W.M. Keck Center for Nano-Scale Imaging
An interdisciplinary research facility in the areas of imaging, nano-science and spectroscopy for measuring surface topography, surface properties, electrical measurements, fluorescence, sub-monolayer visible spectroscopy, and molecular structures.
RRID:SCR_022884
Training, experimental design and/or sample service.
Visit Us!
Location:
Chemical Sciences Bldg. (CSB), Room 135
Hours:
Monday - Friday
8:00 AM to 5:00 PM
24/7 Access for Trained Users
Services
Instrumentation is available on an appointment fee-for-service basis for assisted or unassisted use to all University of Arizona research groups and external customers.
Education/Outreach
The facility hosts an annual summer SPM workshop, free to UArizona students and researchers interested in using SPM as part of their research. The SPM workshop is a week-long lecture and lab workshop in practical scanning probe microscopy with a hands-on training during the lab portion of the workshop, including treatment of scientific digital imaging ethics, and instruction on SPM image data analysis. Contact the manager for information on the next SPM workshop.
Facility Publications
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University of Arizona - UA CBC-W.M. Keck Center for Nano-Scale Imaging, RRID:SCR_022884
203. Bamberger, N. D.; Dyer, D.; Parida, K. N.; El-Assaad, T. H.; Pursell, D.; McGrath, D. V.; Smeu, M.; Monti, O. L. A. Beyond Simple Structure–Function Relationships: The Interplay of Geometry, Electronic Structure, and Molecule/Electrode Coupling in Single-Molecule Junctions. The Journal of Physical Chemistry C 2022, 126 (15), 6653-6661. DOI: 10.1021/acs.jpcc.2c00761.
202. Hong, Z.; Ye, P.; Loy, D. A.; Liang, R. High-Precision Printing of Complex Glass Imaging Optics with Precondensed Liquid Silica Resin. Advanced Science 2022, 9 (18), 2105595. DOI: https://doi.org/10.1002/advs.202105595.
201. Acosta, M. F.; Muralidharan, P.; Grijalva, C. L.; Abrahamson, M. D.; Hayes, D.; Fineman, J. R.; Black, S. M.; Mansour, H. M. Advanced therapeutic inhalation aerosols of a Nrf2 activator and RhoA/Rho kinase (ROCK) inhibitor for targeted pulmonary drug delivery in pulmonary hypertension: design, characterization, aerosolization, in vitro 2D/3D human lung cell cultures, and in vivo efficacy. Therapeutic Advances in Respiratory Disease 2021, 15, 1753466621998245. DOI: 10.1177/1753466621998245.
200. Alabsi, W.; Acosta, M. F.; Al-Obeidi, F. A.; Hay, M.; Polt, R.; Mansour, H. M. Synthesis, Physicochemical Characterization, In Vitro 2D/3D Human Cell Culture, and In Vitro Aerosol Dispersion Performance of Advanced Spray Dried and Co-Spray Dried Angiotensin (1—7) Peptide and PNA5 with Trehalose as Microparticles/Nanoparticles for Targeted Respiratory Delivery as Dry Powder Inhalers. Pharmaceutics 2021, 13 (8), 1278.
199. Alabsi, W.; Al-Obeidi, F. A.; Polt, R.; Mansour, H. M. Organic Solution Advanced Spray-Dried Microparticulate/Nanoparticulate Dry Powders of Lactomorphin for Respiratory Delivery: Physicochemical Characterization, In Vitro Aerosol Dispersion, and Cellular Studies. Pharmaceutics 2021, 13 (1), 26.
198. Alabsi, W. A.-O., F.A.; Polt, R.; Mansour, H.M. . Organic Solution Advanced Spray-Dried Microparticulate/Nanoparticulate Dry Powders of Lactomorphin for Respiratory Delivery: Physicochemical Characterization, In Vitro Aerosol Dispersion, and Cellular Studies. Pharmaceutics 2021, 13 (1), 26. DOI: https://doi.org/10.3390/pharmaceutics13010026.
197. Bamberger, N. D.; Dyer, D.; Parida, K. N.; McGrath, D. V.; Monti, O. L. A. Grid-Based Correlation Analysis to Identify Rare Quantum Transport Behaviors. The Journal of Physical Chemistry C 2021, 125 (33), 18297-18307. DOI: 10.1021/acs.jpcc.1c04794.
196. Davis, G. J.; Townsend, J. A.; Morrow, M. G.; Hamie, M.; Shepard, A. J.; Hsieh, C.-C.; Marty, M. T.; Jewett, J. C. Protein Modification via Mild Photochemical Isomerization of Triazenes to Release Aryl Diazonium Ions. Bioconjugate Chemistry 2021, 32 (11), 2432-2438. DOI: 10.1021/acs.bioconjchem.1c00459.
195. Hong, Z.; Ye, P.; Loy, D. A.; Liang, R. Three-dimensional printing of glass micro-optics. Optica 2021, 8 (6), 904-910. DOI: 10.1364/OPTICA.422955.
194. Ivie, J. A.; Bamberger, N. D.; Parida, K. N.; Shepard, S.; Dyer, D.; Saraiva-Souza, A.; Himmelhuber, R.; McGrath, D. V.; Smeu, M.; Monti, O. L. A. Correlated Energy-Level Alignment Effects Determine Substituent-Tuned Single-Molecule Conductance. ACS Applied Materials & Interfaces 2021. DOI: 10.1021/acsami.0c19404.
193. Kang, K.-S.; Phan, A.; Olikagu, C.; Lee, T.; Loy, D. A.; Kwon, M.; Paik, H.-j.; Hong, S. J.; Bang, J.; Parker Jr., W. O.; et al. Segmented Polyurethanes and Thermoplastic Elastomers from Elemental Sulfur with Enhanced Thermomechanical Properties and Flame Retardancy. Angewandte Chemie International Edition 2021, 60 (42), 22900-22907. DOI: https://doi.org/10.1002/anie.202109115.
192. Muralidharan, P.; Acosta, M. F.; Gomez, A. I.; Grijalva, C.; Tang, H.; Yuan, J. X.-J.; Mansour, H. M. Design and Comprehensive Characterization of Tetramethylpyrazine (TMP) for Targeted Lung Delivery as Inhalation Aerosols in Pulmonary Hypertension (PH): In Vitro Human Lung Cell Culture and In Vivo Efficacy. Antioxidants 2021, 10 (3), 427.
191. Muralidharan, P.; Hayes, D.; Fineman, J. R.; Black, S. M.; Mansour, H. M. Advanced Microparticulate/Nanoparticulate Respirable Dry Powders of a Selective RhoA/Rho Kinase (Rock) Inhibitor for Targeted Pulmonary Inhalation Aerosol Delivery. Pharmaceutics 2021, 13 (12), 2188.
190. Palomares, D.; Ammann, K. R.; Saldana Perez, J. J.; Gomez, A.; Barreda, A.; Russell-Cheung, A.; Martin, A.; Tran, P. L.; Hossainy, S.; Slepian, R. C.; et al. Patterned Electrospinning: A Method of Generating Defined Fibrous Constructs Influencing Cell Adhesion and Retention. ACS Applied Bio Materials 2021, 4 (5), 4084-4093. DOI: 10.1021/acsabm.0c01311.
189. Seaton, B. T.; Heien, M. L. Biocompatible reference electrodes to enhance chronic electrochemical signal fidelity in vivo. Analytical and Bioanalytical Chemistry 2021, 413 (27), 6689-6701. DOI: 10.1007/s00216-021-03640-w.
188. Wijetunge, A. J. D., G. J.*; Shadmehr, M.; Townsend, J. A.; Marty, M. T.; Jewett, J. C. . Copper-Free Click Enabled Triazabutadiene for Bioorthogonal Protein Functionalization. Bioconjugate Chem. 2021, 32, 254-258.
187. Wijetunge, A. N.; Davis, G. J.; Shadmehr, M.; Townsend, J. A.; Marty, M. T.; Jewett, J. C. Copper-Free Click Enabled Triazabutadiene for Bioorthogonal Protein Functionalization. Bioconjugate Chemistry 2021, 32 (2), 254-258. DOI: 10.1021/acs.bioconjchem.0c00677.
186. Acosta, M. F.; Abrahamson, M. D.; Encinas-Basurto, D.; Fineman, J. R.; Black, S. M.; Mansour, H. M. Inhalable Nanoparticles/Microparticles of an AMPK and Nrf2 Activator for Targeted Pulmonary Drug Delivery as Dry Powder Inhalers. Aaps J. 2020, 23 (1), 14, Article. DOI: 10.1208/s12248-020-00531-3.
185. Acosta, M. F.; Muralidhran, P.; Abrahamson, M. D.; Grijalva, C. L.; Carver, M.; Tang, H.; Klinger, C.; Fineman, J. R.; Black, S. M.; Mansour, H. M. Comparison of l-Carnitine and l-Carnitine HCL salt for targeted lung treatment of pulmonary hypertension (PH) as inhalation aerosols: Design, comprehensive characterization, in vitro 2D/3D cell cultures, and in vivo MCT-Rat model of PH. Pulmonary Pharmacology & Therapeutics 2020, 65, 101998. DOI: https://doi.org/10.1016/j.pupt.2021.101998.
184. Arcidiacono, A.; Zhou, Y.; Zhang, W.; Ellison, J. O.; Ayad, S.; Knorr, E. S.; Peters, A. N.; Zheng, L.; Yang, W.; Saavedra, S. S.; et al. Examining the Influence of Bilayer Structure on Energy Transfer and Molecular Photon Upconversion in Metal Ion Linked Multilayers. The Journal of Physical Chemistry C 2020, 124 (43), 23597-23610. DOI: 10.1021/acs.jpcc.0c08715.
183. Arcidiacono, A.; Zhou, Y.; Zhang, W. D.; Ellison, J. O.; Ayad, S.; Knorr, E. S.; Peters, A. N.; Zheng, L. Q.; Yang, W.; Saavedra, S. S.; et al. Examining the Influence of Bilayer Structure on Energy Transfer and Molecular Photon Upconversion in Metal Ion Linked Multilayers. Journal of Physical Chemistry C 2020, 124 (43), 23597-23610, Article. DOI: 10.1021/acs.jpcc.0c08715.
182. AzadiAghdam, M.; Park, M.; Lopez-Prieto, I. J.; Achilli, A.; Snyder, S. A.; Farrell, J. Pretreatment for water reuse using fluidized bed crystallization. J. Water Process. Eng. 2020, 35, 7, Article. DOI: 10.1016/j.jwpe.2020.101226.
181. Bamberger, N. D.; Ivie, J. A.; Parida, K. N.; McGrath, D. V.; Monti, O. L. A. Unsupervised Segmentation-Based Machine Learning as an Advanced Analysis Tool for Single Molecule Break Junction Data. Journal of Physical Chemistry C 2020, 124 (33), 18302-18315, Article. DOI: 10.1021/acs.jpcc.0c03612.
180. Bittner, V. A.; Szarek, M.; Aylward, P. E.; Bhatt, D. L.; Diaz, R.; Edelberg, J. M.; Fras, Z.; Goodman, S. G.; Halvorsen, S.; Hanotin, C.; et al. Effect of Alirocumab on Lipoprotein(a) and Cardiovascular Risk After Acute Coronary Syndrome. J. Am. Coll. Cardiol. 2020, 75 (2), 133-144, Article. DOI: 10.1016/j.jacc.2019.10.057.
179. Davis, G. J.; Sofka, H. A.; Jewett, J. C. Highly Stable Meldrum's Acid Derivatives for Irreversible Aqueous Covalent Modification of Amines. Organic Letters 2020, 22 (7), 2626-2629. DOI: 10.1021/acs.orglett.0c00597.
178. Davis, G. J. S., H. A.; Jewett, J. C. . Highly Stable Meldrum's Acid Derivatives for Irreversible Aqueous Covalent Modification of Amines. Org. Lett. 2020, 22, 2626-2629.
177. Eads, C. N.; Zachritz, S. L.; Park, J.; Chakraborty, A.; Nordlund, D. L.; Monti, O. L. A. Ultrafast Carrier Dynamics in Two-Dimensional Electron Gas-like K-Doped MoS2. Journal of Physical Chemistry C 2020, 124 (35), 19187-19195, Article. DOI: 10.1021/acs.jpcc.0c07079.
176. Gomez, A. I.; Acosta, M. F.; Muralidharan, P.; Yuan, J. X. J.; Black, S. M.; Hayes, D.; Mansour, H. M. Advanced spray dried proliposomes of amphotericin B lung surfactant-mimic phospholipid microparticles/nanoparticles as dry powder inhalers for targeted pulmonary drug delivery. Pulmonary Pharmacology & Therapeutics 2020, 64, 101975. DOI: https://doi.org/10.1016/j.pupt.2020.101975.
175. Hinckley, A. P.; Driskill, M. M.; Muscat, A. J. Dense Organosilane Monolayer Resist That Directs Highly Selective Atomic Layer Deposition. ACS Applied Nano Materials 2020, 3 (4), 3185-3194. DOI: 10.1021/acsanm.9b02128.
174. Kawaguchi, T.; Rollins, M. G.; Moinpour, M.; Morera, A. A.; Ebmeier, C. C.; Old, W. M.; Schwart, J. C. Changes to the TDP-43 and FUS Interactomes Induced by DNA Damage. Journal of Proteome Research 2020, 19 (1), 360-370. DOI: 10.1021/acs.jproteome.9b00575.
173. Kleine, T.; Frish, J. I.; Pavlopoulos, N. G.; Showghi, S. A.; Himmelhuber, R.; Norwood, R. A.; Pyun, J. Refractive Index Contrast Polymers: Photoresponsive Systems with Spatial Modulation of Refractive Index for Photonics. ACS Macro Lett. 2020, 9 (3), 416-421, Article. DOI: 10.1021/acsmacrolett.9b00919.
172. Kleine, T. S.; Glass, R. S.; Lichtenberger, D. L.; Mackay, M. E.; Char, K.; Norwood, R. A.; Pyun, J. 100th Anniversary of Macromolecular Science Viewpoint: High Refractive Index Polymers from Elemental Sulfur for Infrared Thermal Imaging and Optics. ACS Macro Lett. 2020, 9 (2), 245-259, Article. DOI: 10.1021/acsmacrolett.9b00948.
171. Muccianti, C.; Zachritz, S. L.; Garlant, A.; Eads, C. N.; Badada, B. H.; Alfrey, A.; Koehler, M. R.; Mandrus, D. G.; Binder, R.; LeRoy, B. J.; et al. Coupled 2D Semiconductor–Molecular Excitons with Enhanced Raman Scattering. The Journal of Physical Chemistry C 2020, 124 (50), 27637-27644. DOI: 10.1021/acs.jpcc.0c06544.
170. Muralidharan, P.; Jones, B.; Allaway, G.; Biswal, S. S.; Mansour, H. M. Design and development of innovative microparticulate/nanoparticulate inhalable dry powders of a novel synthetic trifluorinated chalcone derivative and Nrf2 agonist. Sci Rep 2020, 10 (1), 15, Article. DOI: 10.1038/s41598-020-76585-2.
169. Muralidharan, P.; Mallory, E. K.; Malapit, M.; Phan, H.; Ledford, J. G.; Hayes, D.; Mansour, H. Advanced design and development of nanoparticle/microparticle dual-drug combination lactose carrier-free dry powder inhalation aerosols. RSC Adv. 2020, 10, 41846-41856. DOI: 10.1039/D0RA07203F.
168. Muralidharan, P.; Mallory, E. K.; Malapit, M.; Phan, H.; Ledford, J. G.; Hayes, D.; Mansour, H. M. Advanced design and development of nanoparticle/microparticle dual-drug combination lactose carrier-free dry powder inhalation aerosols. RSC Adv. 2020, 10 (68), 41846-41856, Article. DOI: 10.1039/d0ra07203f.
167. Rao, P. R.; Muralidharan, K.; Momayez, M.; Runge, K. A.; Loy, D. A. Direct foaming driven synthesis and thermophysical characterization of silica-alumina foams: Applications for thermal insulation. Ceram. Int. 2020, 46 (8), 10431-10441, Article. DOI: 10.1016/j.ceramint.2020.01.042
166. Seaton, B. T.; Hill, D. F.; Cowen, S. L.; Heien, M. L. Mitigating the Effects of Electrode Biofouling-Induced Impedance for Improved Long-Term Electrochemical Measurements In Vivo. Analytical Chemistry 2020, 92 (9), 6334-6340. DOI: 10.1021/acs.analchem.9b05194.
165. Shallcross, R. C.; Graham, A. L.; Karayilan, M.; Pavlopoulous, N. G.; Meise, J.; Pyun, J.; Armstrong, N. R. Influence of the Processing Environment on the Surface Composition and Electronic Structure of Size-Quantized CdSe Quantum Dots. Journal of Physical Chemistry C 2020, 124 (39), 21305-21318, Article. DOI: 10.1021/acs.jpcc.0c05622.
164. Shin, H.; Oh, Y.; Park, C.; Kang, Y.; Cho, H. U.; Blaha, C. D.; Bennet, K. E.; Heien, M. L.; Kim, I. Y.; Lee, K. H.; et al. Sensitive and Selective Measurement of Serotonin in Vivo Using Fast Cyclic Square-Wave Voltammetry. Analytical Chemistry 2020, 92 (1), 774-781. DOI: 10.1021/acs.analchem.9b03164.
163. Stanfill, J. G. Investigations of Hybrid Perovskite Thin Films and Interfacing TiO2 Electrode Surfaces: Chemical Origins of Nanoscale Structural and Electrical Properties for Photovoltaic Applications. University of Arizona, 2020. https://repository.arizona.edu/handle/10150/641356.
162. Wang, S.; Xu, D.; Gurunathan, R.; Snyder, G. J.; Hao, Q. Thermal studies of individual Si/Ge heterojunctions — The influence of the alloy layer on the heterojunction. Journal of Materiomics 2020, 6 (2), 248-255. DOI: https://doi.org/10.1016/j.jmat.2020.02.013.
161. Wang, S.; Xu, D. C.; Gurunathan, R.; Snyder, G. J.; Hao, Q. Thermal studies of individual Si/Ge heterojunctions - The influence of the alloy layer on the heterojunction. Journal of Materiomics 2020, 6 (2), 248-255, Article. DOI: 10.1016/j.jmat.2020.02.013.
160. Xiao, Y.; Xu, D.; Medina, F. J.; Wang, S.; Hao, Q. Thermal studies of nanoporous thin films with added periodic nanopores-a new approach to evaluate the importance of phononic effects. Mater. Today Phys. 2020, 12, 9, Article. DOI: 10.1016/j.mtphys.2020.100179.
159. Zhang, Z. M.; Wang, Y. M.; Watanabe, K.; Taniguchi, T.; Ueno, K.; Tutuc, E.; LeRoy, B. J. Flat bands in twisted bilayer transition metal dichalcogenides. Nat. Phys. 2020, 16 (11), 1093-+, Article. DOI: 10.1038/s41567-020-0958-x.
158. Zheng, Y.; Giordano, A. J.; Marder, S. R.; Saavedra, S. S. Potential-Modulated Total Internal Reflection Fluorescence for Measurement of the Electron Transfer Kinetics of Submonolayers on Optically Transparent Electrodes. Langmuir 2020, 36 (24), 6728-6735. DOI: 10.1021/acs.langmuir.0c00817.
157. Zheng, Y. L.; Giordano, A. J.; Marder, S. R.; Saavedra, S. S. Potential-Modulated Total Internal Reflection Fluorescence for Measurement of the Electron Transfer Kinetics of Submonolayers on Optically Transparent Electrodes. Langmuir 2020, 36 (24), 6728-6735, Article. DOI: 10.1021/acs.langmuir.0c00817.
156. Apostoli, A.; Bianchi, V.; Bono, N.; Dimasi, A.; Ammann, K. R.; Moiia, Y. R.; Montisci, A.; Sheriff, J.; Bluestein, D.; Fiore, G. B.; et al. Prothrombotic activity of cytokine-activated endothelial cells and shear-activated platelets in the setting of ventricular assist device support. J. Heart Lung Transplant. 2019, 38 (6), 658-667, Article. DOI: 10.1016/j.healun.2019.02.009.
155. Ardila, D. C.; Liou, J. J.; Maestas, D.; Slepian, M. J.; Badowski, M.; Wagner, W. R.; Harris, D.; Vande Geest, J. P. Surface Modification of Electrospun Scaffolds for Endothelialization of Tissue-Engineered Vascular Grafts Using Human Cord Blood-Derived Endothelial Cells. J. Clin. Med. 2019, 8 (2), 21, Article. DOI: 10.3390/jcm8020185.
154. Barahona, C. J.; Basantes, L. E.; Tompkins, K. J.; Heitman, D. M.; Chukwu, B. I.; Sanchez, J.; Sanchez, J. L.; Ghadirian, N.; Park, C. K.; Horton, N. C. The Need for Speed: Run-On Oligomer Filament Formation Provides Maximum Speed with Maximum Sequestration of Activity. Journal of Virology 2019, 93 (5). DOI: 10.1128/jvi.01647-18.
153. Daviddi, E.; Chen, Z.; Massani, B. B.; Lee, J.; Bentley, C. L.; Unwin, P. R.; Ratcliff, E. L. Nanoscale Visualization and Multiscale Electrochemical Analysis of Conductive Polymer Electrodes. ACS Nano 2019, 13 (11), 13271-13284, Article. DOI: 10.1021/acsnano.9b06302.
152. Deng, H. K.; Hackney, S. A.; Aifantis, K. E. Fabrication of octagonal and dodecagonal single crystal Si micropyramids via etching without using a pre-patterned mask. Materials Science in Semiconductor Processing 2019, 93, 36-43. DOI: 10.1016/j.mssp.2018.12.017.
151. Finan, E.; Milster, T.; Kim, Y. Adaptive Optics Correction Using Coherently Illuminated Diffractive Objects. In Ods 2019: Industrial Optical Devices and Systems, Katayama, R., Takashima, Y. Eds.; Proceedings of SPIE, Vol. 11125; Spie-Int Soc Optical Engineering, 2019.
150. Fonseka, N. M.; Liang, B.; Orosz, K. S.; Jones, I. W.; Hall, H. K., Jr.; Christie, H. S.; Aspinwall, C. A.; Saavedra, S. S. Nanodomain Formation in Planar Supported Lipid Bilayers Composed of Fluid and Polymerized Dienoyl Lipids. Langmuir 2019, 35 (38), 12483-12491. DOI: 10.1021/acs.langmuir.9b02101.
149. Fonseka, N. M.; Liang, B. Y.; Orosz, K. S.; Jones, I. W.; Hall, H. K.; Christie, H. S.; Aspinwall, C. A.; Saavedra, S. S. Nanodomain Formation in Planar Supported Lipid Bilayers Composed of Fluid and Polymerized Dienoyl Lipids. Langmuir 2019, 35 (38), 12483-12491. DOI: 10.1021/acs.langmuir.9b02101.
148. Goodman, S. G.; Aylward, P. E.; Szarek, M.; Chumburidze, V.; Bhatt, D. L.; Bittner, V. A.; Diaz, R.; Edelberg, J. M.; Hanotin, C.; Harrington, R. A.; et al. Effects of Alirocumab on Cardiovascular Events After Coronary Bypass Surgery. J. Am. Coll. Cardiol. 2019, 74 (9), 1177-1186, Article. DOI: 10.1016/j.jacc.2019.07.015.
147. Hu, Q.; Rezaee, E.; Li, M.; Chen, Q.; Cao, Y.; Mayukh, M.; McGrath, D. V.; Xu, Z.-X. Molecular Design Strategy in Developing Titanyl Phthalocyanines as Dopant-Free Hole-Transporting Materials for Perovskite Solar Cells: Peripheral or Nonperipheral Substituents? ACS Applied Materials & Interfaces 2019, 11 (40), 36535-36543. DOI: 10.1021/acsami.9b09490.
146. Hu, Q. K.; Rezaee, E.; Li, M. Z.; Chen, Q.; Cao, Y.; Mayukh, M.; McGrath, D. V.; Xu, Z. X. Molecular Design Strategy in Developing Titanyl Phthalocyanines as Dopant-Free Hole-Transporting Materials for Perovskite Solar Cells: Peripheral or Nonperipheral Substituents? Acs Applied Materials & Interfaces 2019, 11 (40), 36535-36543, Article. DOI: 10.1021/acsami.9b09490.
145. Islam, A.; Scavello, M.; Lotfi, P.; Daniel, D.; Haldeman, P.; Charest, P. G. Caffeine inhibits PI3K and mTORC2 in Dictyostelium and differentially affects multiple other cAMP chemoattractant signaling effectors. Molecular and Cellular Biochemistry 2019, 457 (1-2), 157-168. DOI: 10.1007/s11010-019-03520-z.
144. Isoe, J.; Koch, L. E.; Isoe, Y. E.; Rascón, A. A., Jr.; Brown, H. E.; Massani, B. B.; Miesfeld, R. L. Identification and characterization of a mosquito-specific eggshell organizing factor in Aedes aegypti mosquitoes. PLOS Biology 2019, 17 (1), e3000068. DOI: 10.1371/journal.pbio.3000068.
143. Jukema, J. W.; Szarek, M.; Zijlstra, L. E.; de Silva, H. A.; Bhatt, D. L.; Bittner, V. A.; Diaz, R.; Edelberg, J. M.; Goodman, S. G.; Hanotin, C.; et al. Alirocumab in Patients With Polyvascular Disease and Recent Acute Coronary Syndrome ODYSSEY OUTCOMES Trial. J. Am. Coll. Cardiol. 2019, 74 (9), 1167-1176, Article. DOI: 10.1016/j.jacc.2019.03.013.
142. Klein, M.; Badada, B. H.; Binder, R.; Alfrey, A.; McKie, M.; Koehler, M. R.; Mandrus, D. G.; Taniguchi, T.; Watanabe, K.; LeRoy, B. J.; et al. 2D semiconductor nonlinear plasmonic modulators. Nat. Commun. 2019, 10, 7, Article. DOI: 10.1038/s41467-019-11186-w.
141. Kleine, T. S.; Lee, T.; Carothers, K. J.; Hamilton, M. O.; Anderson, L. E.; Diaz, L. R.; Lyons, N. P.; Coasey, K. R.; Parker, W. O.; Borghi, L.; et al. Infrared Fingerprint Engineering: A Molecular-Design Approach to Long-Wave Infrared Transparency with Polymeric Materials. Angew. Chem.-Int. Edit. 2019, 58 (49), 17656-17660, Article. DOI: 10.1002/anie.201910856.
140. Nguyen, P. D.; Zhang, X. R.; Su, J. One-Step Controlled Synthesis of Size-Tunable Toroidal Gold Particles for Biochemical Sensing. Acs Applied Nano Materials 2019, 2 (12), 7839-7847. DOI: 10.1021/acsanm.9b01856.
139. Oquendo, L. E.; Ehamparam, R.; Armstrong, N. R.; Saavedra, S. S.; McGrath, D. V. Zinc Phthalocyanine-Phosphonic Acid Monolayers on ITO: Influence of Molecular Orientation, Aggregation, and Tunneling Distance on Charge-Transfer Kinetics. Journal of Physical Chemistry C 2019, 123 (12), 6970-6980. DOI: 10.1021/acs.jpcc.8b10301.
138. Park, H. J.; Wang, W. W.; Curlango-Rivera, G.; Xiong, Z. G.; Lin, Z. R.; Huskey, D. A.; Hawes, M. C.; VanEtten, H. D.; Turgeon, B. G. A DNase from a Fungal Phytopathogen Is a Virulence Factor Likely Deployed as Counter Defense against Host-Secreted Extracellular DNA. Mbio 2019, 10 (2). DOI: 10.1128/mBio.02805-18.
137. Ray, K. K.; Colhoun, H. M.; Szarek, M.; Baccara-Dinet, M.; Bhatt, D. L.; Bittner, V. A.; Budaj, A. J.; Diaz, R.; Goodman, S. G.; Hanotin, C.; et al. Effects of alirocumab on cardiovascular and metabolic outcomes after acute coronary syndrome in patients with or without diabetes: a prespecified analysis of the ODYSSEY OUTCOMES randomised controlled trial. Lancet Diabetes Endocrinol. 2019, 7 (8), 618-628, Article. DOI: 10.1016/s2213-8587(19)30158-5.
136. Roe, M. T.; Li, Q. H.; Bhatt, D. L.; Bittner, V. A.; Diaz, R.; Goodman, S. G.; Harrington, R. A.; Jukema, J. W.; Lopez-Jaramillo, P.; Lopes, R. D.; et al. Risk Categorization Using New American College of Cardiology/American Heart Association Guidelines for Cholesterol Management and Its Relation to Alirocumab Treatment Following Acute Coronary Syndromes. Circulation 2019, 140 (19), 1578-1589, Article. DOI: 10.1161/circulationaha.119.042551.
135. Rudolph, M.; Harris, J. K.; Ratcliff, E. L. Printable transistors for wearable sweat sensing. In Smart Biomedical and Physiological Sensor Technology Xv, Cullum, B. M., Kiehl, D., McLamore, E. S. Eds.; Proceedings of SPIE, Vol. 11020; Spie-Int Soc Optical Engineering, 2019.
134. Rudolph, M.; Harris, J. K.; Ratcliff, E. L. Predicting limits of detection in real-time sweat-based human performance monitoring. In Smart Biomedical and Physiological Sensor Technology Xv, Cullum, B. M., Kiehl, D., McLamore, E. S. Eds.; Proceedings of SPIE, Vol. 11020; Spie-Int Soc Optical Engineering, 2019.
133. Sang, L.; Pemberton, J. E. Penetration and Reaction Depths of Vapor Deposited Ag, Mg, Al, and Ca on Oligothiophene Thin Films. Chemistry of Materials 2019, 31 (17), 6908-6917. DOI: 10.1021/acs.chemmater.9b01313.
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55. Muriithi, B.; Loy, D. A. Proton conductivity of Nafion/ex situ Stober silica nanocomposite membranes as a function of silica particle size and temperature. Journal of Materials Science 2014, 49 (4), 1566-1573. DOI: 10.1007/s10853-013-7839-y.
54. Simmonds, A. G.; Griebel, J. J.; Park, J.; Kim, K. R.; Chung, W. J.; Oleshko, V. P.; Kim, J.; Kim, E. T.; Glass, R. S.; Soles, C. L.; et al. Inverse Vulcanization of Elemental Sulfur to Prepare Polymeric Electrode Materials for Li-S Batteries. ACS Macro Lett. 2014, 3 (3), 229-232. DOI: 10.1021/mz400649w.
53. Vreeland, R. F.; Laude, N. D.; Lambert, S. M.; Heien, M. L. Microwave-Plasma Dry-Etch for Fabrication of Conducting Polymer Microelectrodes. Analytical Chemistry 2014, 86 (3), 1385-1390. DOI: 10.1021/ac403363a.
52. Zhou, Y.; Bright, L. K.; Shi, W. Q.; Aspinwall, C. A.; Baker, L. A. Ion Channel Probes for Scanning Ion Conductance Microscopy. Langmuir 2014, 30 (50), 15351-15355. DOI: 10.1021/la504097f.
51. Baker, C. A.; Bright, L. K.; Aspinwall, C. A. Photolithographic Fabrication of Microapertures with Well-Defined, Three-Dimensional Geometries for Suspended Lipid Membrane Studies. Analytical Chemistry 2013, 85 (19), 9078-9086. DOI: 10.1021/ac401639n.
50. Bright, L. K.; Baker, C. A.; Agasid, M. T.; Ma, L.; Aspinwall, C. A. Decreased Aperture Surface Energy Enhances Electrical, Mechanical, and Temporal Stability of Suspended Lipid Membranes. Acs Applied Materials & Interfaces 2013, 5 (22), 11918-11926. DOI: 10.1021/am403605h.
49. Chung, W. J.; Griebel, J. J.; Kim, E. T.; Yoon, H.; Simmonds, A. G.; Ji, H. J.; Dirlam, P. T.; Glass, R. S.; Wie, J. J.; Nguyen, N. A.; et al. The use of elemental sulfur as an alternative feedstock for polymeric materials. Nature Chemistry 2013, 5 (6), 518-524. DOI: 10.1038/nchem.1624.
48. Cocilovo, B.; Amooali, A.; Lopez-Santiago, A.; Favela, J.; Islam, S.; Duong, B.; Gangopadhyay, P.; Fallahi, M.; Pemberton, J. E.; Thomas, J.; et al. Effect of modular diffraction gratings on absorption in P3HT:PCBM layers. Applied Optics 2013, 52 (5), 1025-1034. DOI: 10.1364/ao.52.001025.
47. Gliboff, M.; Sang, L.; Knesting, K. M.; Schalnat, M. C.; Mudalige, A.; Ratcliff, E. L.; Li, H.; Sigdel, A. K.; Giordano, A. J.; Berry, J. J.; et al. Orientation of Phenylphosphonic Acid Self-Assembled Monolayers on a Transparent Conductive Oxide: A Combined NEXAFS, PM-IRRAS, and DFT Study. Langmuir 2013, 29 (7), 2166-2174. DOI: 10.1021/la304594t.
46. Han, Z. X.; Keswani, M.; Raghavan, S. Megasonic Cleaning of Blanket and Patterned Samples in Carbonated Ammonia Solutions for Enhanced Particle Removal and Reduced Feature Damage. Ieee Transactions on Semiconductor Manufacturing 2013, 26 (3), 400-405. DOI: 10.1109/tsm.2013.2271641.
45. Kolsch, V.; Shen, Z. X.; Lee, S.; Plak, K.; Lotfi, P.; Chang, J.; Charest, P. G.; Romero, J. L.; Jeon, T. J.; Kortholt, A.; et al. Daydreamer, a Ras effector and GSK-3 substrate, is important for directional sensing and cell motility. Molecular Biology of the Cell 2013, 24 (2), 100-114. DOI: 10.1091/mbc.E12-04-0271.
44. Li, G. X.; Wie, J. J.; Nguyen, N. A.; Chung, W. J.; Kim, E. T.; Char, K.; Mackay, M. E.; Pyun, J. Synthesis, self-assembly and reversible healing of supramolecular perfluoropolyethers. Journal of Polymer Science Part a-Polymer Chemistry 2013, 51 (17), 3598-3606. DOI: 10.1002/pola.26777.
43. Li, Z.; Tolbert, S.; Loy, D. A. Hybrid Organic-Inorganic Membranes on Porous Supports by Size Exclusion and Thermal Sintering of Fluorescent Polyphenylsilsesquioxane Nanoparticles. Macromolecular Materials and Engineering 2013, 298 (7), 715-721. DOI: 10.1002/mame.201200091.
42. Ou, K. L.; Tadytin, D.; Steirer, K. X.; Placencia, D.; Nguyen, M.; Lee, P.; Armstrong, N. R. Titanium dioxide electron-selective interlayers created by chemical vapor deposition for inverted configuration organic solar cells. Journal of Materials Chemistry A 2013, 1 (23), 6794-6803. DOI: 10.1039/c3ta10894e.
41. Sherwood, C. L.; Liguori, A. E.; Olsen, C. E.; Lantz, R. C.; Burgess, J. L.; Boitano, S. Arsenic Compromises Conducting Airway Epithelial Barrier Properties in Primary Mouse and Immortalized Human Cell Cultures. Plos One 2013, 8 (12). DOI: 10.1371/journal.pone.0082970.
40. Steirer, K. X.; MacDonald, G. A.; Olthof, S.; Gantz, J.; Ratcliff, E. L.; Kahn, A.; Armstrong, N. R. Energy Level Alignment and Morphology of Ag and Au Nanoparticle Recombination Contacts in Tandem Planar Heterojunction Solar Cells. Journal of Physical Chemistry C 2013, 117 (43), 22331-22340. DOI: 10.1021/jp402672j.
39. Lin, H. C.; Polaske, N. W.; Oquendo, L. E.; Gliboff, M.; Knesting, K. M.; Nordlund, D.; Ginger, D. S.; Ratcliff, E. L.; Beam, B. M.; Armstrong, N. R.; et al. Electron-Transfer Processes in Zinc Phthalocyanine Phosphonic Acid Monolayers on ITO: Characterization of Orientation and Charge-Transfer Kinetics by Waveguide Spectroelectrochemistry. Journal of Physical Chemistry Letters 2012, 3 (9), 1154-1158. DOI: 10.1021/jz3002426.
38. MacDonald, G. A.; Veneman, R. A.; Placencia, D.; Armstrong, N. R. Electrical Property Heterogeneity at Transparent Conductive Oxide/Organic Semiconductor Interfaces: Mapping Contact Ohmicity Using Conducting-Tip Atomic Force Microscopy. ACS Nano 2012, 6 (11), 9623-9636. DOI: 10.1021/nn303043y.
37. Matz, D. L.; Pemberton, J. E. Reaction Chemistry of Solid-State Pyridine Thin Films with Vapor Deposited Ag, Mg, and Al. Journal of Physical Chemistry C 2012, 116 (21), 11548-11555. DOI: 10.1021/jp300795c.
36. Muriithi, B.; Loy, D. A. Processing, Morphology, and Water Uptake of Nafion/Ex situ Stober Silica Nanocomposite Membranes As a Function of Particle Size. Acs Applied Materials & Interfaces 2012, 4 (12), 6765-6772. DOI: 10.1021/am301931e.
35. Santamaría, J.; Brusseau, M. L.; Araujo, J.; Orosz-Coghlan, P.; Blanford, W. J.; Gerba, C. P. Transport and Retention of Cryptosporidium Parvum Oocysts in Sandy Soils. Journal of Environmental Quality 2012, 41 (4), 1246-1252. DOI: https://doi.org/10.2134/jeq2011.0414.
34. Thanu, D. P. R.; Raghavan, S.; Keswani, M. Effect of Water Addition to Choline Chloride-Urea Deep Eutectic Solvent (DES) on the Removal of Post-Etch Residues Formed on Copper. Ieee Transactions on Semiconductor Manufacturing 2012, 25 (3), 516-522. DOI: 10.1109/tsm.2012.2190998.
33. Ashton, J. H.; Mertz, J. A. M.; Harper, J. L.; Slepian, M. J.; Mills, J. L.; McGrath, D. V.; Vande Geest, J. P. Polymeric endoaortic paving: Mechanical, thermoforming, and degradation properties of polycaprolactone/polyurethane blends for cardiovascular applications. Acta Biomaterialia 2011, 7 (1), 287-294. DOI: 10.1016/j.actbio.2010.09.004.
32. Ge, C. H.; Orosz, K. S.; Armstrong, N. R.; Saavedra, S. S. Poly(aniline) Nanowires in Sol-Gel Coated ITO: A pH-Responsive Substrate for Planar Supported Lipid Bilayers. Acs Applied Materials & Interfaces 2011, 3 (7), 2677-2685. DOI: 10.1021/am2004637.
31. Mayukh, M.; Lu, C. W.; Hernandez, E.; McGrath, D. V. Peripheral Substitution of a Near-IR-Absorbing Soluble Phthalocyanine Using "Click" Chemistry. Chemistry-a European Journal 2011, 17 (30), 8472-8478. DOI: 10.1002/chem.201001427.
30. Natividad, S. L.; Marotto, V. R.; Walker, L. S.; Pham, D.; Pinc, W.; Corral, E. L. Tape Casting Thin, Continuous, Homogenous, and Flexible Tapes of ZrB2. Journal of the American Ceramic Society 2011, 94 (9), 2749-2753. DOI: 10.1111/j.1551-2916.2011.04690.x.
29. Pinc, W. R.; Di Prima, M.; Walker, L. S.; Wing, Z. N.; Corral, E. L. Spark Plasma Joining of ZrB2-SiC Composites Using Zirconium-Boron Reactive Filler Layers. Journal of the American Ceramic Society 2011, 94 (11), 3825-3832. DOI: 10.1111/j.1551-2916.2011.04739.x.
28. Placencia, D.; Wang, W. N.; Gantz, J.; Jenkins, J. L.; Armstrong, N. R. Highly Photoactive Titanyl Phthalocyanine Polymorphs as Textured Donor Layers in Organic Solar Cells. Journal of Physical Chemistry C 2011, 115 (38), 18873-18884. DOI: 10.1021/jp2052085.
27. Wang, W. N.; Placencia, D.; Armstrong, N. R. Planar and textured heterojunction organic photovoltaics based on chloroindium phthalocyanine (ClInPc) versus titanyl phthalocyanine (TiOPc) donor layers. Organic Electronics 2011, 12 (2), 383-393. DOI: 10.1016/j.orgel.2010.11.015.
26. Zacher, B.; Armstrong, N. R. Modeling the Effects of Molecular Length Scale Electrode Heterogeneity in Organic Solar Cells. Journal of Physical Chemistry C 2011, 115 (51), 25496-25507. DOI: 10.1021/jp207471f.
25. Bao, W. Z.; Liu, G.; Zhao, Z.; Zhang, H.; Yan, D.; Deshpande, A.; LeRoy, B. J.; Lau, C. N. Lithography-free fabrication of high quality substrate-supported and freestanding graphene devices. Nano Research 2010, 3 (2), 98-102. DOI: 10.1007/s12274-010-1013-5.
24. Baughman, K. F.; Maier, R. M.; Norris, T. A.; Beam, B. M.; Mudalige, A.; Pemberton, J. E.; Curry, J. E. Evaporative Deposition Patterns of Bacteria from a Sessile Drop: Effect of Changes in Surface Wettability Due to Exposure to a Laboratory Atmosphere. Langmuir 2010, 26 (10), 7293-7298. DOI: 10.1021/la100932k.
23. Kim, B. Y.; Ratcliff, E. L.; Armstrong, N. R.; Kowalewski, T.; Pyun, J. Ferrocene Functional Polymer Brushes on Indium Tin Oxide via Surface-Initiated Atom Transfer Radical Polymerization. Langmuir 2010, 26 (3), 2083-2092. DOI: 10.1021/la902590u.
22. Kumaran, N.; Veneman, P. A.; Minch, B. A.; Mudalige, A.; Pemberton, J. E.; O'Brien, D. F.; Armstrong, N. R. Self-Organized Thin Films of Hydrogen-Bonded Phthalocyanines: Characterization of Structure and Electrical Properties on Nanometer Length Scales. Chemistry of Materials 2010, 22 (8), 2491-2501. DOI: 10.1021/cm903127w.
21. Mayukh, M.; Sema, C. M.; Roberts, J. M.; McGrath, D. V. Solvent-Free Synthesis of Soluble, Near-IR Absorbing Titanyl Phthalocyanine Derivatives. Journal of Organic Chemistry 2010, 75 (22), 7893-7896. DOI: 10.1021/jo1011637.
20. Munro, A. M.; Zacher, B.; Graham, A.; Armstrong, N. R. Photoemission Spectroscopy of Tethered CdSe Nanocrystals: Shifts in Ionization Potential and Local Vacuum Level As a Function of Nanocrystal Capping Ligand. Acs Applied Materials & Interfaces 2010, 2 (3), 863-869. DOI: 10.1021/am900834y.
19. Price, J.; Barnett, J.; Raghavan, S.; Keswani, M.; Govindarajan, R. A study of the interaction of gallium arsenide with wet chemical formulations using thermodynamic calculations and spectroscopic ellipsometry. Microelectronic Engineering 2010, 87 (9), 1661-1664. DOI: 10.1016/j.mee.2009.11.046.
18. Rauf, F.; Huang, Y. D.; Muhandiramlage, T. P.; Aspinwall, C. A. Analysis of protein kinase A activity in insulin-secreting cells using a cell-penetrating protein substrate and capillary electrophoresis. Analytical and Bioanalytical Chemistry 2010, 397 (8), 3359-3367. DOI: 10.1007/s00216-010-3776-7.
17. Schalnat, M. C.; Pemberton, J. E. Comparison of a Fluorinated Aryl Thiol Self-Assembled Monolayer with Its Hydrogenated Counterpart on Polycrystalline Ag Substrates. Langmuir 2010, 26 (14), 11862-11869. DOI: 10.1021/la1010314.
16. Warren, P. D.; McGrath, D. V.; Geest, J. P. V. Effect of Crosslinker Length and Composition on the Hydrophobicity and Thermomechanical Response of Acrylate-Based Shape-Memory Polymers. Macromolecular Materials and Engineering 2010, 295 (4), 386-396. DOI: 10.1002/mame.200900348.
15. Beam, B. M.; Armstrong, N. R.; Mendes, S. B. An electroactive fiber optic chip for spectroelectrochemical characterization of ultra-thin redox-active films. Analyst 2009, 134 (3), 454-459. DOI: 10.1039/b814338b.
14. Chen, X. C.; Thomas, J.; Gangopadhyay, P.; Norwood, R. A.; Peyghambarian, N.; McGrath, D. V. Modification of Symmetrically Substituted Phthalocyanines Using Click Chemistry: Phthalocyanine Nanostructures by Nanoimprint Lithography. Journal of the American Chemical Society 2009, 131 (38), 13840-13843. DOI: 10.1021/ja905683g.
13. D'Ambruoso, G. D.; Ross, E. E.; Armstrong, N. R.; McGrath, D. V. Site-isolated, intermolecularly photocrosslinkable and patternable dendritic quinacridones. Chemical Communications 2009, (22), 3222-3224. DOI: 10.1039/b901897b.
12. Hong, J. S.; Pyun, J.; Park, Y. W.; Kim, C. S.; Shim, I. B. Oxidation Effect in Cobalt Nanoparticles Magnetic Fluids. Ieee Transactions on Magnetics 2009, 45 (6), 2464-2466. DOI: 10.1109/tmag.2009.2018613.
11. Junkin, M.; Watson, J.; Geest, J. P. V.; Wong, P. K. Template-Guided Self-Assembly of Colloidal Quantum Dots Using Plasma Lithography. Advanced Materials 2009, 21 (12), 1247-+. DOI: 10.1002/adma.200802122.
10. Keng, P. Y.; Kim, B. Y.; Shim, I.-B.; Sahoo, R.; Veneman, P. E.; Armstrong, N. R.; Yoo, H.; Pemberton, J. E.; Bull, M. M.; Griebel, J. J.; et al. Colloidal Polymerization of Polymer-Coated Ferromagnetic Nanoparticles into Cobalt Oxide Nanowires. ACS Nano 2009, 3 (10), 3143-3157. DOI: 10.1021/nn900483w.
9. Keng, P. Y.; Kim, B. Y.; Shim, I. B.; Sahoo, R.; Veneman, P. E.; Armstrong, N. R.; Yoo, H.; Pemberton, J. E.; Bull, M. M.; Griebel, J. J.; et al. Colloidal Polymerization of Polymer-Coated Ferromagnetic Nanoparticles into Cobalt Oxide Nanowires. ACS Nano 2009, 3 (10), 3143-3157. DOI: 10.1021/nn900483w.
8. Keswani, M.; Raghavan, S.; Deymier, P.; Verhaverbeke, S. Megasonic cleaning of wafers in electrolyte solutions: Possible role of electro-acoustic and cavitation effects. Microelectronic Engineering 2009, 86 (2), 132-139. DOI: 10.1016/j.mee.2008.09.042.
7. Macech, P.; Pemberton, J. E. Passivation of pinhole defect microelectrode arrays in ultrathin silica films immobilized on gold substrates. Thin Solid Films 2009, 517 (18), 5399-5403. DOI: 10.1016/j.tsf.2009.01.057.
6. Placencia, D.; Wang, W. N.; Shallcross, R. C.; Nebesny, K. W.; Brumbach, M.; Armstrong, N. R. Organic Photovoltaic Cells Based On Solvent-Annealed, Textured Titanyl Phthalocyanine/C-60 Heterojunctions. Advanced Functional Materials 2009, 19 (12), 1913-1921. DOI: 10.1002/adfm.200801723.
5. Shallcross, R. C.; Chawla, G. S.; Marikkar, F. S.; Tolbert, S.; Pyun, J.; Armstrong, N. R. Efficient CdSe Nanocrystal Diffraction Gratings Prepared by Microcontact Molding. ACS Nano 2009, 3 (11), 3629-3637. DOI: 10.1021/nn900735y.
4. Zhang, H.; Orosz, K. S.; Takahashi, H.; Saavedra, S. S. Broadband Plasmon Waveguide Resonance Spectroscopy for Probing Biological Thin Films. Applied Spectroscopy 2009, 63 (9), 1062-1067. DOI: 10.1366/000370209789379295.
3. Jenkins, J. L.; Ratcliff, E. L.; Shallcross, R. C.; Head, J. L.; Armstrong, N. R. Photovoltaic devices created from electrodeposited, "nano-textured" poly(thiophene) films. In Nanoscale Photonic and Cell Technologies for Photovoltaics, Tsakalakos, L. Ed.; Proceedings of SPIE, Vol. 7047; 2008.
2. Ratcliff, E. L.; Jenkins, J. L.; Nebesny, K.; Armstrong, N. R. Electrodeposited, "textured" poly(3-hexyl-thiophene) (e-P3HT) films for photovoltaic applications. Chemistry of Materials 2008, 20 (18), 5796-5806. DOI: 10.1021/cm8008122.
1. Veneman, A.; Zacher, B.; Huebner, D.; Simmonds, A.; Armstrong, N. R. A planar integrated photometer/refractometer using an organic light emitting diode light source and an organic photovoltaic detector. In Organic Field-Effect Transistors Vii and Organic Semiconductors in Sensors and Bioelectronics, Bao, Z., McCulloch, I., Shinar, R., Malliaras, G. G. Eds.; Proceedings of SPIE, Vol. 7054; 2008